Electrochemical Thin Films at and above the Classical Limiting Current
نویسندگان
چکیده
منابع مشابه
Electrochemical Thin Films at and above the Classical Limiting Current
We study a model electrochemical thin film at DC currents exceeding the classical diffusion-limited value. The mathematical problem involves the steady Poisson–Nernst–Planck equations for a binary electrolyte with nonlinear boundary conditions for reaction kinetics and Stern-layer capacitance, as well as an integral constraint on the number of anions. At the limiting current, we find a nested b...
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ژورنال
عنوان ژورنال: SIAM Journal on Applied Mathematics
سال: 2005
ISSN: 0036-1399,1095-712X
DOI: 10.1137/040609926